The central theme of the Ardo Group's research program is to understand and control reaction mechanisms at interfaces, with the goal of maximizing energy-conversion efficiency for realistic applications, including solar fuels devices, photovoltaics, solar seawater desalination, redox flow batteries, and fuel cells.

Asymmetry is the key characteristic responsible for light-induced charge separation and current rectification; it is present in semiconductors, biological membranes, and molecular donor–chromophore–acceptor complexes. Members of the Ardo Group design and control asymmetry through modeling, synthesis, and engineering of molecule–material structures. The electrochemical, photoelectrochemical, and photophysical properties of hard and soft material interfaces are manipulated via molecular functionalization, electrostatic engineering, and physical protection. New materials and molecules are being investigated, including photoacidic materials, multiple-electron-transfer oxidation catalysts, infrared-absorbing dyes, anion-conducting metal–organic frameworks, and functionalized monolayer materials. The results from each study are pertinent to fundamental electrochemistry and charge-transfer, energy-transfer, and ion-transfer phenomena.

The Ardo Group is well-suited for students and postdoctoral scholars with various backgrounds and expertise, spanning the disciplines of chemistry, materials science, chemical engineering, physics, and biology.
Group News

8/12/2016: Team Ardo makes dye-sensitized solar cells using blackberry dyes with 3rd – 5th grade teachers in Orange County through the ESCAPE program at UCI. Thank you, Joseph, Chris, David, Kevin, Arielle, Brenna, Simon, and Vivian!

8/11/2016: Shane presents a poster award talk at the Gordon Research Conference on Electron Donor-Acceptor Interactions in Newport, RI. Congratulations, Shane!

8/1/2016: Kevin, Sam, Andy, and Anni successfully demonstrate our proposed outreach activity by electrodialyzing acid from a central compartment of a three-compartment cell. Go Team!
De-acidified central compartment relative to outer compartments using electrodialysis

7/28/2016: William Sheu joins Team Ardo. Welcome, William!

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