The central theme of the Ardo Group's research program is to understand and control reaction mechanisms at interfaces, with the goal of maximizing energy-conversion efficiency for realistic applications, including solar fuels devices, photovoltaics, solar seawater desalination, redox flow batteries, and fuel cells.

Dye-Modified Ion-Exchange Membranes

Asymmetry is the key characteristic responsible for light-induced charge separation and current rectification; it is present in semiconductors, biological membranes, and molecular donor–chromophore–acceptor complexes. Members of the Ardo Group design and control asymmetry through modeling, synthesis, and engineering of molecule–material structures. The electrochemical, photoelectrochemical, and photophysical properties of hard and soft material interfaces are manipulated via molecular functionalization and electrostatic engineering. New materials and molecules are being investigated, including photoacidic materials, multiple-electron-transfer oxidation catalysts, infrared-absorbing dyes, chemically modified surfaces, and ion-conducting metal–organic frameworks. The results from each study are pertinent to fundamental electrochemistry and charge-transfer, energy-transfer, and ion-transfer phenomena.

The Ardo Group is well-suited for students and postdoctoral scholars with various backgrounds and expertise, spanning the disciplines of chemistry, materials science, chemical engineering, physics, electrical engineering, and biology.
Group News

2/2/2017: Shane hosts Mike Rose who visits UCI as part of the UCI Department of Chemistry Inorganic Seminar Series to talk about molecular hydride-transfer catalysts and semiconductor photoelectrochemistry with the Ardo Group and others. Thanks for the great visit and thought-provoking seminar, Mike!
Jenny, Mike, and Shane in Jenny's house

1/27/2017: Shane presents an invited keynote university seminar in the Department of Chemical and Biological Engineering at the University of British Columbia as part of their annual Research Day. Thanks for the invitation and wonderful time, Roza, Danielle, other members of the Organizing Team, and Curtis!
CHEM248 Discussion Section Activity

1/23/2017: Shane and Bill hold their first hands-on discussion section for the graduate-level Electrochemistry course.
CHEM248 Discussion Section Activity

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