Publications

Updated September 2023

Alan F. Heyduk


  • "Two-Electron Mixed Valency in a Heterotrimetallic Nickel–Vanadium–Nickel Complex," M.K. Wojnar, J. W. Ziller, and A. F. Heyduk Inorg. Chem. 2023, 62, 4, 1405-1413.
  • "Exploring Ligand-Centered Hydride and H-Atom Transfer," B.J. Charette, J. W. Ziller, and A. F. Heyduk Inorg. Chem. 2021, 60, 7, 5367-5375.
  • "Metal-Ion Influence on Ligand-Centered Hydrogen-Atom Transfer," B.J. Charette, J. W. Ziller, and A. F. Heyduk Inorg. Chem. 2021, 60, 3, 1579-1589.
  • "Redox-Active Catecholate-Type Ligands," A.F. Heyduk and B.J Charette, Comprehensive Coordination Chemistry III. 2021, 650-666.
  • "Hydrogen-Atom Noninnocence of a Tridentate [SNS] Pincer Ligand," K. E. Rosenkoetter, M. K. Wojnar, B. J. Charette, J. W. Ziller, and A. F. Heyduk Inorg. Chem. 2018, 57, 9728-9737.
  • "Three Oxidation States of the Bis(3,5-di-tert-butyl-2-phenolato)azanido Pincer Ligand on Chromium(III)," A. M. Hollas,J. W. Ziller, and A. F. Heyduk Polyhedron 2018, 143, 111-117."
  • "Heterobimetallic and Heterotrimetallic Clusters Containing a Redox-Active Metalloligand," M. K. Wojnar, J. W. Ziller, and A. F. Heyduk Eur. J. Inorg. Chem. 2017, 47, 5571-5575.
  • "Heterobimetallic Complexes of Palladium and Platinum Containing a Redox-Active W[SNS]2 Metalloligand," K. E. Rosenkoetter, J. W. Ziller, and A. F. Heyduk Dalton Trans. 2017, 46, 5503-5507.
  • "A Heterobimetallic W-Ni Complex Containing a Redox-Active W[SNS]2 Metalloligand," K. E. Rosenkoetter, J. W. Ziller, and A. F. Heyduk, Inorg. Chem. 2016, 55, 6794-6798.
  • "Near-IR Absorbing Donor-Acceptor Ligand-to-Ligand Charge-Transfer Complexes of Nickel(II)," L. A. Cameron, J. W. Ziller, and A. F. Heyduk, Chem. Sci. 2016, 7, 1807-1814.
  • "Bimetallic Iron-Iron and Iron-Zinc Complexes of the Redox-Active ONO Pincer Ligand," J. L. Wong, R. F. Higgins, I. Bhowmick, D. X. Cao, G. Szigethy, J. W. Ziller, M. P. Shores, and A. F. Heyduk, Chem. Sci. 2016, 7, 1594-1599.
  • "Synthesis of Catecholate Ligands with Phosphonate Anchoring Groups," E. Seraya, Z. Luan, M. Law, and A. F. Heyduk, Inorg. Chem. 2015, 54, 7571-7578.
  • "Metal Effects on Ligand Non-Innocence In Group 5 Complexes of the Redox-Active [ONO] Pincer Ligand," S. Hananouchi, B. T. Krull, J. W. Ziller, F. Furche, and A. F. Heyduk, Dalton Trans. 2014, 43, 17991-18000.
  • "Donor-Acceptor Ligand-to-Ligand Charge-Transfer Coordination Complexes of Nickel(II)," W. W. Kramer, L. A. Cameron, R. A. Zarkesh, J. W. Ziller, and A. F. Heyduk, Inorg. Chem. 2014, 53, 8825-8837.
  • "Tuning the Electronic and Steric Parameters of a Redox-Active Tris(amido) Ligand," R. F. Munha, R. A. Zarkesh, and A. F. Heyduk, Inorg. Chem. 2013, 52, 11244-11255.
  • "Disulfide Reductive Elimination From an Iron(III) Complex," J. L. Wong, R. H. Sanchez, J. G. Logan, R. A. Zarkesh, J. W. Ziller, and A. F. Heyduk, Chem. Sci. 2013, 4, 1906-1910.
  • "Synthesis and Characterization of Redox-Active Bis(thiophenolato)amide Ligand, [SNS]3-, and the Homoleptic Tungsten Complexes, W[SNS]2 and W[ONO]2," D. W. Shaffer, G. Szigethy, J. W. Ziller, and A. F. Heyduk, Inorg. Chem. 2013, 52, 2110-2118.
  • "Group transfer reactions of d0 transition metal complexes: redox-active ligands provide a mechanism for expanded reactivity," R. F. Munha,R. A. Zarkesh, and A. F. Heyduk, Dalton Trans. 2013, 43, 3751-3766.
  • "Aluminum complexes of the redox-active [ONO] pincer ligand," G. Szigethy and A. F. Heyduk, Dalton Trans. 2012, 41, 8144-8152.
  • "Ligand Effects on the Oxidative Addition of Halogens to (dppnacnacR)Rh(phdi)," D. W. Shaffer, S. A. Ryken, R. A. Zarkesh, and A. F. Heyduk, Inorg. Chem. 2012, 51 (22), 12122-12131.
  • "A Redox-Active Ligand as a Reservoir for Protons and Electrons: O2 Reduction at Zirconium(IV)," F. Lu, R. A. Zarkesh, and A. F. Heyduk, Eur. J. Inorg. Chem. 2012, 3, 467-470.
  • "Coordination Effects on Electron Distributions for Rhodium Complexes of the Redox-Active Bis(3,5-di-tert-butyl-2-phenolate)amide Ligand," G. Szigethy, D. W. Shaffer, and A. F. Heyduk, Inorg. Chem. 2012, 51 (23), 12606-12618.
  • "Reactivity of Organometallic Tantalum Complexes Containing a Bis(phenoxy)amide (ONO)3- Ligand with Aryl Azides and 1,2-Diphenlhydrazine," R. A. Zarkesh, and A. F. Heyduk, Organometallics 2011, 30, 4890-4894.
  • "Designing Catalysts for Nitrene Transfer Using Early Transition Metals and Redox-Active Ligands," A. F. Heyduk, R. A. Zarkesh, and A. I. Nguyen, Inorg. Chem. 2011, 50 (20), 9849-9863.
  • "Steric and Electronic Consequences of Flexibility in a Tetradentate Redox-Active Ligand: Ti(IV) and Zr(IV) Complexes," G. Szigethy and A. F. Heyduk, Inorg. Chem. 2011, 50 (1), 125-135.
  • "Catalytic nitrene transfer by a zirconium(IV) redox-active ligand complex," A. I. Nguyen, R. A. Zarkesh, D. C. Lacy, M. K Thorson, and A. F. Heyduk, Chem. Sci. 2011, 2, 166-169.
  • "Redox Behavior of Rhodium 9,10-Phenanthrenediimine Complexes," D. W. Shaffer, S. A. Ryken, R. A. Zarkesh, and A. F. Heyduk, Inorg. Chem. 2011, 50 (1), 13-21.
  • "Steric Control of Coordination Geometry in Titanium-Imido Complexes of N,N '-bis(arylimino)acenaphthylene Ligands," K. M. Clark, J. W. Ziller, and A. F. Heyduk, Inorg. Chem. 2010, 49, 2222-2231.
  • "Reactivity of Diazoalkanes with Tantalum(V) Complexes of a Tridentate Amido-Bis(phenolate) Ligand," R. A. Zarkesh, and A. F. Heyduk, Organometallics 2009, 28, 6629-6631.
  • "One- and Two-Electron Reactivity of a Tantalum(V) Complex with a Redox-Active Tris(amido) Ligand," A. I. Nguyen, K. J. Blackmore, S. M. Carter, R. A. Zarkesh, and A. F. Heyduk, J. Am. Chem. Soc. 2009,131, 3307-3316.
  • "Group IV Coordination Chemistry of a Tetradentate Redox-Active Ligand in Two Oxidation States," K. J. Blackmore, N. Lal, J. W. Ziller, and A. F. Heyduk, Eur. J. Inorg. Chem. 2009, 735-743.
  • "Synthesis, structure and magnetism of a {Mn[NNO]}10 wheel," J. A. Hoshiko, G. Wang, J. W. Ziller, G. T. Yee, and A. F. Heyduk, Dalton Trans. 2008, 5712-5714.
  • "Synthesis and Characterization of Group IV Bis(Imino-Semiquinone) Complexes Obtained by Oxidative Addition of Halogens," K. J. Blackmore, M. B. Sly, M. R. Haneline, J. W. Ziller, and A. F. Heyduk, Inorg. Chem. 2008, 47, 10522-10532.
  • "N-tert-butyl ortho-aminophenol, ortho-iminoquinone, and a zirconium(IV) bis(aminophenol) complex," K. J. Blackmore, A. I. Nguyen, and A. F. Heyduk, Inorg. Synth. (in press).
  • "Four-Electron Oxidative Formation of Aryl Diazenes Using a Tantalum Redox-Active Ligand Complex," R. A. Zarkesh, J. W. Ziller, and A. F. Heyduk, Angew. Chem. Int. Ed. 2008, 47, 4715-4718.
  • "Isolation and Characterization of a Neutral Imino-Semiquinone Radical," S. A. Carter, A. Sia, M. J. Shaw, and A. F. Heyduk, J. Am. Chem. Soc. 2008, 130, 5838-5839.
  • "Bonding Interactions Generated by Halogen Oxidation of Zirconium(IV) Redox-Active Ligand Complexes," N. A. Ketterer, H. Fan, K. J. Blackmore, X. Yang, J. W. Ziller, M.-H. Baik, and A. F. Heyduk, J. Am. Chem. Soc. 2008, 130, 4364-4374.
  • "Catalytic Reactivity of a Zirconium(IV) Redox-Active Ligand Complex with 1,2-Diphenylhydrazine," K. J. Blackmore, N. Lal, J. W. Ziller, and A. F. Heyduk, J. Am. Chem. Soc. 2008, 130, 2728-2729.
  • "Lithium-Alkyl, -Aryl, and -Amido Ligand Exchange Dynamics of Dianionic Zirconium(IV) Complexes with Chelating Amidophenolate Ligands," K. J. Blackmore, J. W. Ziller, and A. F. Heyduk, Inorg. Chem. 2008, 47, 265-273.
  • "Imido and Organometallic-Amido Titanium(IV) Complexes of a Chelating Phenanthrenediamide Ligand," N. A. Ketterer, J. W. Ziller, A. L. Rheingold, and A. F. Heyduk, Organometallics 2007, 26, 5330-5338.
  • "Bond-Forming Reductive Elimination from a Zirconium(IV) Redox-Active Ligand Complex," M. R. Haneline and A. F. Heyduk, J. Am. Chem. Soc. 2006, 128, 8410-8411.
  • "Oxidative Addition to a Zirconium(IV) Redox-Active Ligand Complex," K. J. Blackmore, J. W. Ziller, and A. F. Heyduk, Inorg. Chem. 2005, 44, 5559-5561.
  • "Azide Addition to Give a Tetra-azazirconacycle Complex," A. F. Heyduk, K. J. Blackmore, N. A. Ketterer, and J. W. Ziller, Inorg. Chem. 2005, 44, 468-470.