Advancements in material science and microscopy has allowed for the interrogation of single-emitter fluorescence for the better part of two decades, leading to advances in many areas including bio-imaging, super-resolution imaging techniques, and photonics. However, many aspects of SM phenomena are not yet fully understood, for example, fluorescence intermittency or the observation of telegraph-like switches in emission intensities (commonly referred to as “blinking”) is a most ubiquitous phenomena observed in SM measurements.