We use ultrafast spectroscopy to study and control the excited-state dynamics of a common photochromic molecular switch. The compound undergoes reversible electrocyclization and cycloreversion reactions that convert the molecule between open- and closed-ring states with very different electronic and optical properties. Our experiments use various excitation schemes to explore different regions of the excited-state potential energy surfaces in order to probe the non-adiabatic dynamics of both the forward and reverse reactions.
We will show certain physical characteristics that leads to strong
near-field field enhancement in plasmonic nanostructures using
collective resonances. The structures considered generally involve two
or a collection of plasmonic nanosctarrers, that sometimes are arrayed
or clustered to generate even stronger collective resonance.
Based on simulations, strong field enhancement will be related to
possible enhancement of the excitation and emission rate of organic
molecules besides clustered structures. The possibility to generate
Nanoscale Gold in Passive and Active Forms: Lessons and Prospects from Computational Studies
Hannu Häkkinen
Departments of Physics and Chemistry, Nanoscience Center, University of Jyväskylä, FI-40014 Jyväskylä,
Finland, hannu.hakkinen@jyu.fi