Ligand and Cluster-size Effects in Metal-mediated Activation of
Methane: A Cold Approach to a Hot Problem1)
Maria Schlangen and Helmut Schwarz
Institut für Chemie der Technischen Universität Berlin, 10623 Berlin, Germany, e-mail:
Helmut.Schwarz@mail.chem.tu-berlin.de
State-of-the-art gas-phase experiments complemented by DFT and electronic structure
calculations of mass-selected, electronic ground-state transition-metal complexes provide
insight into fundamental aspects of elementary steps involved in the activation and
functionalization of methane at ambient temper