Optical nanoantennas provide a rich control over light at nanoscale to achieve high field enhancement and localization with a large absorption cross-sections. Considering the need for these virtues in broad range of fields the possible applications of these nanoantennas span into the fields of spectroscopy, photovoltaics, single photon sources, biological sensing.
Protein-protein interactions within the myocardium have been investigated for over a century, and new information is being elucidated regarding the mechanisms that underlie cardiac contractions. As such, this area of research continues to grow as scientists find novel mechanisms, proteins, and methods of analysis to investigate this process. As a faculty member at Albany State University, Dr.
Recently picosecond vibrationally resonant sum frequency generation (VRSFG) process has been adopted as a surface sensitive, chemically specific nonlinear imaging modality. In this talk, we will discuss our recent efforts to extend this technique to femtosecond regime. To this end, we have built a high powered mid infrared femtosecond optical parametric oscillator (OPO) tunable from 3-5 micron range. Use of femtosecond laser pulses exploits the broad bandwidth of mid infrared pulses to multiplex spectrum measurement and time resolve vibrational free induction decay to study dynamics.
An atomistic electrodynamics model, where the NPs in terms of a macroscopic homogenous dielectric constant is replaced by an atomic representation with dielectric properties depending on the local chemical environment, successfully describes the plasmonics behavior in quantum size region. By using this model, we explored the near field fluctuation and the origin of the SERS varying with time evolution.
Coupling femtosecond pulses to the scanning tunneling microscope (STM) has the potential to combine unprecedented spatial and temporal resolution. Although much progress has been made, there are significant challenges that lie ahead. In this talk, I will highlight our efforts in studying the interactions between laser pulses and single molecules in the STM nanogap junction. I will also discuss the directions we are headed in to further our understanding of molecular dynamics using laser pulses. Challenges, successes and failures will be presented.
One of the main goals of the CaSTL center is to explore chemistry at the space-time limit. Researchers in the center have developed many new and exciting experimental techniques that produce rich chemical information. The Schatz group has been working to connect theory with CaSTL experiments using a variety of analytic, electronic structure, and electrodynamic theories.
In recent advancement of nonlinear plasmonics and metamaterials, significant near-field enhancement by localized surface plasmon resonance (LSPR) of noble metal nanostructure array plays a key role. It is important to better understand the fundamental relationship between LSPR and the induced nonlinear polarization. In this talk, we will discuss the second-order nonlinear optical properties of plasmonic gold nanocrescent array whose LSPR can be selectively excited by tuning the wavelength and polarization of incident electric field.
Asymmetric dimer nanocrescents fabricated using copper mask nanosphere template lithography elicit giant circular dichroism (CD) responses. Chiro-optical activity, commonly used to distinguish between molecular chiral enantiomers, illustrates light-matter interactions that depend dramatically on plasmonic structural characteristics. Dimer nanocrescents exhibit enhanced chiro-optical activity and switches in CD handedness relative to tilt.