Events in inorganic chemistry.

Photoredox Bond-Forming Reactions: From Nickel to Naphthol Catalysts

Abstract: Photoredox catalysis has continued to gain attention for its ability to perform previously unachieved reactivity in the fields of renewable fuels and organic synthesis. In general, photoredox systems offer a potentially sustainable route to drive single-electron transfers to activate a secondary catalyst for small molecule activations and bond forming reactions. Our group have developed a photoredox system with secondary nickel catalysts capable of C-C, C-N, and N-N bonds.

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