Abstract: Polymers have become a ubiquitous part of our lives, filling diverse applications ranging from aerospace to children’s toys. With over three hundred million tons of plastics being produced annually, it is crucial to increase their usable lifespan and reduce their relegation to waste. As such, it is necessary to move away from traditional commodity polymers and steer towards new structural designs that resist deterioration and failure. For wider adoption, these new structural designs should be thermally stable, resistant to additives, and resist/repair damage.