PhD defenses.

Probing the Role of Steric and Electronic Effects on the Synthesis, Properties, and Reactivity of Low Oxidation State Rare-Earth and Actinide Metal Complexes

Abstract: Ever since Lappert and coworkers isolated the first examples of crystallographically characterizable La(II) and Ce(II) complexes in 2008, molecular complexes containing rare-earth metals in the +2 oxidation state have been isolated for the rest of the series, except for radioactive Pm.

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